why does mercury have a convex meniscus

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A convex meniscus occurs when the molecules have a stronger attraction to each other (cohesion) than to the material of the container (adhesion), causing the surface of the liquid to cave downward. When the weight of the liquid in the tube generates a downward force equal to the upward force associated with capillary action, the liquid stops rising. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Tom (and mike) (published on 10/22/2007) Follow-up on this answer. has a convex shape because the cohesive forces in liquid mercury tend to Why might a cell need to use the enzyme pepsin? It can be either convex or concave. Among common liquids, water exhibits a distinctly high surface tension due to strong hydrogen bonding between its molecules. What are the physical properties of mercury? and glass. What is Meniscus? When the molecules of the liquid have a greater attraction to the cylinder wall than to themselves, the meniscus is concave and the surface of the liquid curved downwards. On smaller raindrops, the surface tension is stronger than in larger drops. Mercury therefore does not wet glass, and it forms a convex meniscus when confined in a tube because the cohesive forces within the mercury tend to draw it into a drop (Figure \(\PageIndex{4}\)). (credit: Mark Ott). What characteristics allow plants to survive in the desert? - A meniscus for aqueous solutions is always convex. The strong adhesive forces between the water and the glass, pull the sides of the water upwards along the glass forming a concave shaped meniscus. The meniscus of a liquid is the upward or downward curve seen at the top of a liquid in a container. It does not store any personal data. The cookie is used to store the user consent for the cookies in the category "Other. 4 What liquids have a concave meniscus? Water meniscus is convex, mercury menisucs is concave A concave meniscus, which is what you normally will see, occurs when the molecules of the liquid are attracted to those of the container. When mercury is put in a measuring cylinder, the meniscus curves downwards. Convex menisci are read from the top of the curve at eye level. The smaller the diameter of the tube is, the higher the liquid climbs. as possible to be in contact with the container. In the case of liquids like mercury that form a convex meniscus, use the top of the convex meniscus. When liquid mercury is confined in a tube, its surface (meniscus) has a convex shape because the cohesive forces in liquid mercury tend to draw it into a drop. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Why? In liquids such as water, the meniscus is concave; in liquids such as mercury, however, which have very strong cohesive forces and weak adhesion to glass, the meniscus is convex . Why? Water spreads out on glass because the adhesive force between water and glass is greater than the cohesive forces within the water. The smaller the diameter of the tube, the higher the liquid rises. Being a heavy, silvery d-block element, mercury is the only metal that is liquid at standard temperature and pressure conditions. Complete answer: In a subsequent video the same person attributes the phenomenon to mercury's high surface tension and non-wetting, non-wicking chemistry. However, in mercury, th cohesive force are stronger than the adhesive forces. Video \(\PageIndex{1}\): An overview of intermolecular forces in action as surface tension, viscosity, and capillary action. As such, it is one of the four fundamental states of matter (the others being solid, gas, and plasma), and is the only state with a definite volume but no fixed shape. Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. Both consist of long molecules of cellulose that contain many OH groups. This procedure can be easily done because of capillary action, the ability of a liquid to flow up a small tube against gravity, as shown in Figure \(\PageIndex{7}\). The water molecules are also attracted to each other, so large amounts of water are drawn up the cellulose fibers. have very small adhesive forces with water , and if you make a container out of these you will get a convex meniscus with water, too. The strong cohesive forces within the mercury pull it together forming a convex shaped meniscus. These cookies ensure basic functionalities and security features of the website, anonymously. and the container, also known as "wetting", encourages as much liquid What are various methods available for deploying a Windows application? In such a case, the liquid forms a concave meniscus. Why is the meniscus of water curved upwards? The reverse is true for mercury put in a glass tube. In such a case the liquid forms a convex meniscus. 4 Why are mercury and water droplets almost spherical? creeps up the side. Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors. How many lines of symmetry does a star have? The mercury in a glass flask is a good example of the effects of the relationship between cohesive and adhesive forces. The cookie is used to store the user consent for the cookies in the category "Analytics". Why water in a narrow glass tube has a concave meniscus? liquid leaving the minimum number of molecules on the surface. Why? Examples in humans are found in the wrist, knee, temporomandibular, and sternoclavicular joints. A meniscus occurs because of surface tension in the liquid and must be read at eye level. 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When you have mercury liquid in a container, why is the meniscus upside down compared to all other liquids? A meniscus is a fibrocartilaginous tissue. 12201 Sunrise Valley Drive Reston, VA 20192. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The water molecules are attracted to each other through cohesion, which is the attraction between similar particles (by polarity). A molecule at the surface of a liquid experiences only net inward cohesive forces. Why method like Kjeldahl and Dumas are used in determining protein content? It can be either concave or convex. The cookie is used to store the user consent for the cookies in the category "Performance". Mercury forms a convex meniscus as there is a strong attractive force between the molecules of mercury than the force between the molecule and the walls of the container. Copyright 2023 Quick-Advice.com | All rights reserved. Water, gasoline, and other liquids that flow freely have a low viscosity. Science. Found a typo and want extra credit? The inward forces on the surface molecules of a liquid drop tend to cause the surface to volume ratio as small as possible. What are some examples of properties of liquids? A similar process occurs in a cloth towel when you use it to dry off after a shower. Little drops of mercury will form into almost spheres when spilled on most surfaces (gravity will bend them out of shape). In either case, you are measuring based on the center of the meniscus. 2 How is the meniscus of mercury different to that of water? Click here. Therefore mercury falls down from the sides attach to the wall and a concave or upward meniscus is obtained. The adhesive forces between the liquid and the porous material, combined with the cohesive forces within the liquid, may be strong enough to move the liquid upward against gravity. A convex meniscus occurs when the molecules have a stronger attraction to each other than to the container, as with mercury and glass. It can be either concave or convex, depending on the liquid and the surface. Mercury shows a convex meniscus (the centre is higher than the edges), because internal cohesive forces are stronger than the force between the glass wall and the metal. Official websites use .gov When the tube is made of a material to which the liquid molecules are strongly attracted, they will spread out completely on the surface, which corresponds to a contact angle of 0. By clicking Accept All, you consent to the use of ALL the cookies. (credit: modification of work by Centers for Disease Control and Prevention). A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. A 55-cm high object is placed 15 cm in front of the mirror. A convex meniscus occurs when the molecules have a stronger attraction to each other than to the container, as with mercury and glass. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. Usually placing the container on a lab bench does the trick. Figure \(\PageIndex{6}\): Depending upon the relative strengths of adhesive and cohesive forces, a liquid may rise (such as water) or fall (such as mercury) in a glass capillary tube. Figure \(\PageIndex{1}\): (a) Honey and (b) motor oil are examples of liquids with high viscosities; they flow slowly. The gaps between the salt grains are smaller than the radius of this meniscus, so the mercury can't flow between them . Consequently, why Mercury has its meniscus upward? For water, adhesive force is stronger than the cohesive forces, sticking more strongly to the capillary wall than other water molecules, hence as the tube is thinner, the higher the level. Therefore mercury falls down from the sides attach to the wall and a concave or upward meniscus is obtained. Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. When mercury is put in a measuring cylinder, the meniscus curves downwards. Why might a consumer buy locally sourced food? However, in mercury, th cohesive force are stronger than the adhesive forces. The meniscus plays a vital role in maintaining the stability of the knee joint along with optimizing the tibiofemoral load transfer and distribution. 7 Why is the meniscus of water concave and of? Why the free surface of water is concave but that of Mercury is convex? The upper surface of a liquid in a tube is called the meniscus, and the shape of the meniscus depends on the relative strengths of the cohesive and adhesive forces. stick to the container.) Mercury metal is more attracted to itself than to the walls of the glass manometer. When water is confined in a glass tube, its meniscus (surface) has a concave shape because the water wets the glass and creeps up the side of the tube. When liquid mercury is confined in a tube, its surface (meniscus) has a convex shape because the cohesive forces in liquid mercury tend to draw it into a drop. 6 What kind of meniscus does mercury form? Why does water in a graduated cylinder form a meniscus? What happens when Mercury is placed in a graduated cylinder? 6 Why does liquid rise in a capillary tube? Water meniscus is concave, mercury meniscus is convex. 9 What causes a glass tube to form an inverted meniscus? We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Surface tension, which arises due to the The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Why is the meniscus of water concave and of? the adhesive forces between the molecules of a liquid and those of the Capillary action can also occur when one end of a small diameter tube is immersed in a liquid, as illustrated in Figure \(\PageIndex{6}\). The strong cohesive forces within the mercury pull it together forming a convex shaped meniscus. Hereof, what causes a convex meniscus?The meniscus is the curve caused by surface tension in the upper . We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Why methyl orange turns yellow when you add it to an alkaline solution? We also use third-party cookies that help us analyze and understand how you use this website. arrow_forward A convex mirror has a radius of curvature of 30 cm. University of Illinois at Urbana-Champaign. convex meniscus Mercury metal forms a convex meniscus in glass vessels. Due to its high cohesion and low adhesion to glass, mercury does not spread to cover the surface of the flask. The cookie is used to store the user consent for the cookies in the category "Analytics". Necessary cookies are absolutely essential for the website to function properly. surface (meniscus) has a concave shape because water wets the surface and In contrast, water exhibits a concave meniscus, because the attraction between the wall and the water is stronger than the water's internal cohesion. Figure \(\PageIndex{5}\): Wine wicks up a paper towel (left) because of the strong attractions of water (and ethanol) molecules to the OH groups on the towels cellulose fibers and the strong attractions of water molecules to other water (and ethanol) molecules (right). It See all questions in Properties of Solids, Liquids, and Gases. Figure \(\PageIndex{4}\) : Differences in the relative strengths of cohesive and adhesive forces result in different meniscus shapes for mercury (left . It does not store any personal data. Concave menisci are read from the bottom of the curve at eye level. | Angle of contact: Obtuse, zero and 90 degree | 2020 Your Physics Class 4.82K subscribers Subscribe 2.1K views 2 years ago Mechanical Properties of. Mercury shows a convex meniscus (the centre is higher than the edges), because internal cohesive forces are stronger than the force between the glass wall and the metal. A convex meniscus occurs when the molecules have a stronger attraction to each other than to the container, as with mercury and glass. Why might a labor supply curve be backward bending? Ashesive forces act between water molecules and glass molecules. and cohesive forces of the liquid are balanced by the weight of the liquid. By clicking Accept All, you consent to the use of ALL the cookies. The meniscus (plural: menisci, from the Greek for "crescent") is the curve in the upper surface of a liquid to the surface of the container or another object. Ans: Because cohesive force between molecules of mercury is greater than the adhesive force between mercury and glass molecules. When liquid mercury is confined in a tube, its surface (meniscus) The surface tension of a liquid results from an imbalance of intermolecular attractive forces, the cohesive forces between molecules: A molecule in the bulk liquid experiences cohesive forces with other molecules in all directions. Conversely, a concave meniscus occurs when the molecules of the liquid attract those of the containers, causing the surface of the liquid to cave downwards. *Impurities present in a liquid appreciably affect surface tension. You can get a concave and convex meniscus. These cookies will be stored in your browser only with your consent. The nature of curve whether upward (convex) or downward (concave) depends on the surface tension the liquid and its adhesion capacity to the wall of the container. 6 Why is the meniscus of water curved upwards? There are two types of meniscus lenses- concave and convex. There are two types of meniscus lenses- concave and convex. Therefore mercury falls down from the sides attach to the wall and a concave or upward meniscus is obtained. Metallic bonding clearly accounts for the convex meniscus observed in mercury metal in glass vessels. area of a liquid by a unit of area. (credit photo: modification of work by Mark Blaser). The meniscus (plural: menisci, from the Greek for "crescent") is the curve in the upper surface of a liquid close to the surface of the container or another object, caused by surface tension. When mercury is placed in a graduated cylinder, the cohesive forces in the mercury are stronger than the adhesive forces between the mercury and the glass. Larger drops are more greatly affected by gravity, air resistance, surface interactions, and so on, and as a result, are less spherical. How is a meniscus read? forces within the drops are stronger than the adhesive forces between the Adhesion of water to the walls of the capillary tube will lead to an upward force on the liquid at the edges. A meniscus is a curve formed on the upper surface of a liquid inside a container. A meniscus lens is a concave-convex lens where one of the faces is curved inward and another face is curved outward. . What is the shape when a mercury is placed in a glass vessel? adhesive forces between the liquid and the glass are stronger than the 7.1: Surface Tension, Viscosity, and Capillary Action is shared under a CC BY license and was authored, remixed, and/or curated by LibreTexts. These cookies will be stored in your browser only with your consent. Why does Mercury have a convex meniscus in a tube? Because mercury still exhibits metallic bonding, even in the liquid state, and metal-metal interactions are stronger than the metal glass interactions. 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why does mercury have a convex meniscus


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